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Alternative Fuels in Fire Debris Analysis: Biodiesel Basics

NCJ Number
217652
Journal
Journal of Forensic Sciences Volume: 52 Issue: 2 Dated: March 2007 Pages: 371-379
Author(s)
Eric Stauffer M.S.; Doug Byron B.S.
Date Published
March 2007
Length
9 pages
Annotation
This paper instructs fire-debris analysts in the history, features, and production of biodiesel fuel, as well as procedures for extracting it from fire debris and analyzing it.
Abstract
Biodiesel is part of the family of biofuels and is a term used to define a fuel produced from a biological source (vegetable oils and/or animal oils/fats) that is used in lieu of diesel fuel. Biodiesel fuel is composed of fatty acid methyl esters (FAMEs) and is sold pure or as a blend with diesel fuel. Fire debris analysts are taught that most ignitable liquid residues they will encounter are petroleum-based liquids. This will likely be the case for many years to come. A few liquids, mostly oxygenated compounds and wood distillates (terpenes), are not petroleum-based and are encountered by fire-debris analysts sporadically. With the rapid emergence of alternative fuels, however, it is likely that unknown liquids or fire debris that contains such fuels will be submitted to the crime laboratory more often for examination. Biodiesel fuel is readily identified by gas chromatography-mass spectrometry. It can be extracted from fire debris samples by passive headspace concentration on activated charcoal strips; however, a solvent extraction that uses a nonpolar solvent is more suitable for this type of fluid. The analyst must be careful not to miss a possible mixture of biodiesel fuel with other ignitable liquid residues when interpreting the results of such analyses. 2 tables, 5 figures, and 39 references